AZ 59 then FR 6926 at Fiumicino
Madrid → Rome → Barcelona
Timetable, Rome time
08:15AZ 59 from Madrid at the gate
21:50FR 6926 to Barcelona leaves the gate
13 h 35 apart on the timetable
FR 6926 leaves 13 h 35 after AZ 59 arrives on the timetable: more than half a day, so not a connection we count.