AZ 61 then EW 9885 at Fiumicino
Madrid → Rome → Düsseldorf
Timetable, Rome time
14:00AZ 61 from Madrid at the gate
10:30EW 9885 to Düsseldorf leaves the gate
20 h 30 apart on the timetable, overnight
EW 9885 leaves 20 h 30 after AZ 61 arrives on the timetable: more than half a day, so not a connection we count.