AZ 61 then FR 4891 at Fiumicino
Madrid → Rome → Catania
Timetable, Rome time
14:00AZ 61 from Madrid at the gate
12:15FR 4891 to Catania leaves the gate
22 h 15 apart on the timetable, overnight
FR 4891 leaves 22 h 15 after AZ 61 arrives on the timetable: more than half a day, so not a connection we count.