AZ 621 then FR 9601 at Fiumicino
Los Angeles → Rome → Madrid
Timetable, Rome time
12:20AZ 621 from Los Angeles at the gate
10:40FR 9601 to Madrid leaves the gate
22 h 20 apart on the timetable, overnight
FR 9601 leaves 22 h 20 after AZ 621 arrives on the timetable: more than half a day, so not a connection we count.