AZ 63 then FR 3074 at Fiumicino
Madrid → Rome → Brindisi
Timetable, Rome time
20:30AZ 63 from Madrid at the gate
12:35FR 3074 to Brindisi leaves the gate
16 h 05 apart on the timetable, overnight
FR 3074 leaves 16 h 05 after AZ 63 arrives on the timetable: more than half a day, so not a connection we count.