AZ 63 then FR 5842 at Fiumicino
Madrid → Rome → Brindisi
Timetable, Rome time
20:30AZ 63 from Madrid at the gate
14:50FR 5842 to Brindisi leaves the gate
18 h 20 apart on the timetable, overnight
FR 5842 leaves 18 h 20 after AZ 63 arrives on the timetable: more than half a day, so not a connection we count.