AZ 631 then FR 9601 at Fiumicino
Miami → Rome → Madrid
Timetable, Rome time
11:40AZ 631 from Miami at the gate
09:00FR 9601 to Madrid leaves the gate
21 h 20 apart on the timetable, overnight
FR 9601 leaves 21 h 20 after AZ 631 arrives on the timetable: more than half a day, so not a connection we count.