AZ 641 then FR 9601 at Fiumicino
San Francisco → Rome → Madrid
Timetable, Rome time
12:15AZ 641 from San Francisco at the gate
10:40FR 9601 to Madrid leaves the gate
22 h 25 apart on the timetable, overnight
FR 9601 leaves 22 h 25 after AZ 641 arrives on the timetable: more than half a day, so not a connection we count.