AZ 679 then FR 5316 at Fiumicino
São Paulo → Rome → Madrid
Timetable, Rome time
11:35AZ 679 from São Paulo at the gate
10:20FR 5316 to Madrid leaves the gate
22 h 45 apart on the timetable, overnight
FR 5316 leaves 22 h 45 after AZ 679 arrives on the timetable: more than half a day, so not a connection we count.