AZ 77 then FR 9601 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
13:25AZ 77 from Barcelona at the gate
06:10FR 9601 to Madrid leaves the gate
16 h 45 apart on the timetable, overnight
FR 9601 leaves 16 h 45 after AZ 77 arrives on the timetable: more than half a day, so not a connection we count.