EW 886 then FR 999 at Fiumicino
Cologne → Rome → Valencia
Timetable, Rome time
08:55EW 886 from Cologne at the gate
22:45FR 999 to Valencia leaves the gate
13 h 50 apart on the timetable
FR 999 leaves 13 h 50 after EW 886 arrives on the timetable: more than half a day, so not a connection we count.