EW 886 then U2 2965 at Fiumicino
Cologne → Rome → Berlin
Timetable, Rome time
19:00EW 886 from Cologne at the gate
17:30U2 2965 to Berlin leaves the gate
22 h 30 apart on the timetable, overnight
U2 2965 leaves 22 h 30 after EW 886 arrives on the timetable: more than half a day, so not a connection we count.