EW 8882 then FR 3946 at Fiumicino
Berlin → Rome → Palermo
Timetable, Rome time
09:40EW 8882 from Berlin at the gate
05:45FR 3946 to Palermo leaves the gate
20 h 05 apart on the timetable, overnight
FR 3946 leaves 20 h 05 after EW 8882 arrives on the timetable: more than half a day, so not a connection we count.