EW 8882 then FR 993 at Fiumicino
Berlin → Rome → Valencia
Timetable, Rome time
09:40EW 8882 from Berlin at the gate
09:20FR 993 to Valencia leaves the gate
23 h 40 apart on the timetable, overnight
FR 993 leaves 23 h 40 after EW 8882 arrives on the timetable: more than half a day, so not a connection we count.