EW 8882 then OS 554 at Fiumicino
Berlin → Rome → Vienna
Timetable, Rome time
17:15EW 8882 from Berlin at the gate
15:05OS 554 to Vienna leaves the gate
21 h 50 apart on the timetable, overnight
OS 554 leaves 21 h 50 after EW 8882 arrives on the timetable: more than half a day, so not a connection we count.