FR 1000 then FR 3074 at Fiumicino
Valencia → Rome → Brindisi
Timetable, Rome time
10:00FR 1000 from Valencia at the gate
05:50FR 3074 to Brindisi leaves the gate
19 h 50 apart on the timetable, overnight
FR 3074 leaves 19 h 50 after FR 1000 arrives on the timetable: more than half a day, so not a connection we count.