FR 1004 then AZ 76 at Fiumicino
Valencia → Rome → Barcelona
Timetable, Rome time
15:15FR 1004 from Valencia at the gate
14:05AZ 76 to Barcelona leaves the gate
22 h 50 apart on the timetable, overnight
AZ 76 leaves 22 h 50 after FR 1004 arrives on the timetable: more than half a day, so not a connection we count.