FR 1004 then FR 5842 at Fiumicino
Valencia → Rome → Brindisi
Timetable, Rome time
19:25FR 1004 from Valencia at the gate
14:50FR 5842 to Brindisi leaves the gate
19 h 25 apart on the timetable, overnight
FR 5842 leaves 19 h 25 after FR 1004 arrives on the timetable: more than half a day, so not a connection we count.