FR 1004 then IB 650 at Fiumicino
Valencia → Rome → Madrid
Timetable, Rome time
15:15FR 1004 from Valencia at the gate
14:45IB 650 to Madrid leaves the gate
23 h 30 apart on the timetable, overnight
IB 650 leaves 23 h 30 after FR 1004 arrives on the timetable: more than half a day, so not a connection we count.