FR 1004 then UX 1042 at Fiumicino
Valencia → Rome → Madrid
Timetable, Rome time
19:25FR 1004 from Valencia at the gate
15:55UX 1042 to Madrid leaves the gate
20 h 30 apart on the timetable, overnight
UX 1042 leaves 20 h 30 after FR 1004 arrives on the timetable: more than half a day, so not a connection we count.