FR 3075 then FR 5316 at Fiumicino
Brindisi → Rome → Madrid
Timetable, Rome time
14:35FR 3075 from Brindisi at the gate
10:20FR 5316 to Madrid leaves the gate
19 h 45 apart on the timetable, overnight
FR 5316 leaves 19 h 45 after FR 3075 arrives on the timetable: more than half a day, so not a connection we count.