FR 3180 then AZ 58 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
09:50FR 3180 from Barcelona at the gate
08:20AZ 58 to Madrid leaves the gate
22 h 30 apart on the timetable, overnight
AZ 58 leaves 22 h 30 after FR 3180 arrives on the timetable: more than half a day, so not a connection we count.