FR 3180 then FR 41 at Fiumicino
Barcelona → Rome → Berlin
Timetable, Rome time
11:15FR 3180 from Barcelona at the gate
09:45FR 41 to Berlin leaves the gate
22 h 30 apart on the timetable, overnight
FR 41 leaves 22 h 30 after FR 3180 arrives on the timetable: more than half a day, so not a connection we count.