FR 3180 then FR 9601 at Fiumicino
Barcelona → Rome → Madrid
Timetable, Rome time
11:15FR 3180 from Barcelona at the gate
10:40FR 9601 to Madrid leaves the gate
23 h 25 apart on the timetable, overnight
FR 9601 leaves 23 h 25 after FR 3180 arrives on the timetable: more than half a day, so not a connection we count.