FR 3180 then U2 5080 at Fiumicino
Barcelona → Rome → Berlin
Timetable, Rome time
08:00FR 3180 from Barcelona at the gate
20:45U2 5080 to Berlin leaves the gate
12 h 45 apart on the timetable
U2 5080 leaves 12 h 45 after FR 3180 arrives on the timetable: more than half a day, so not a connection we count.