FR 4857 then EW 8883 at Fiumicino
Catania → Rome → Berlin
Timetable, Rome time
12:35FR 4857 from Catania at the gate
10:20EW 8883 to Berlin leaves the gate
21 h 45 apart on the timetable, overnight
EW 8883 leaves 21 h 45 after FR 4857 arrives on the timetable: more than half a day, so not a connection we count.