FR 5180 then W4 6253 at Fiumicino
Alicante → Rome → Palermo
Timetable, Rome time
20:50FR 5180 from Alicante at the gate
18:00W4 6253 to Palermo leaves the gate
21 h 10 apart on the timetable, overnight
W4 6253 leaves 21 h 10 after FR 5180 arrives on the timetable: more than half a day, so not a connection we count.