FR 5315 then AZ 672 at Fiumicino
Madrid → Rome → Rio De Janeiro
Timetable, Rome time
08:55FR 5315 from Madrid at the gate
22:30AZ 672 to Rio De Janeiro leaves the gate
13 h 35 apart on the timetable
AZ 672 leaves 13 h 35 after FR 5315 arrives on the timetable: more than half a day, so not a connection we count.