FR 5315 then EW 9885 at Fiumicino
Madrid → Rome → Düsseldorf
Timetable, Rome time
11:15FR 5315 from Madrid at the gate
10:30EW 9885 to Düsseldorf leaves the gate
23 h 15 apart on the timetable, overnight
EW 9885 leaves 23 h 15 after FR 5315 arrives on the timetable: more than half a day, so not a connection we count.