FR 5315 then W4 3966 at Fiumicino
Madrid → Rome → Chişinău
Timetable, Rome time
20:30FR 5315 from Madrid at the gate
19:05W4 3966 to Chişinău leaves the gate
22 h 35 apart on the timetable, overnight
W4 3966 leaves 22 h 35 after FR 5315 arrives on the timetable: more than half a day, so not a connection we count.