FR 5315 then W4 6103 at Fiumicino
Madrid → Rome → Prishtina
Timetable, Rome time
20:30FR 5315 from Madrid at the gate
19:15W4 6103 to Prishtina leaves the gate
22 h 45 apart on the timetable, overnight
W4 6103 leaves 22 h 45 after FR 5315 arrives on the timetable: more than half a day, so not a connection we count.