FR 7067 then FR 9601 at Fiumicino
Brindisi → Rome → Madrid
Timetable, Rome time
08:45FR 7067 from Brindisi at the gate
06:00FR 9601 to Madrid leaves the gate
21 h 15 apart on the timetable, overnight
FR 9601 leaves 21 h 15 after FR 7067 arrives on the timetable: more than half a day, so not a connection we count.