FR 9602 then AZ 1745 at Fiumicino
Madrid → Rome → Catania
Timetable, Rome time
16:40FR 9602 from Madrid at the gate
13:20AZ 1745 to Catania leaves the gate
20 h 40 apart on the timetable, overnight
AZ 1745 leaves 20 h 40 after FR 9602 arrives on the timetable: more than half a day, so not a connection we count.