FR 9602 then BA 561 at Fiumicino
Madrid → Rome → London Heathrow
Timetable, Rome time
22:10FR 9602 from Madrid at the gate
20:40BA 561 to London Heathrow leaves the gate
22 h 30 apart on the timetable, overnight
BA 561 leaves 22 h 30 after FR 9602 arrives on the timetable: more than half a day, so not a connection we count.