FR 9602 then FR 4114 at Fiumicino
Madrid → Rome → Katowice
Timetable, Rome time
11:45FR 9602 from Madrid at the gate
10:00FR 4114 to Katowice leaves the gate
22 h 15 apart on the timetable, overnight
FR 4114 leaves 22 h 15 after FR 9602 arrives on the timetable: more than half a day, so not a connection we count.