FR 9602 then UA 885 at Fiumicino
Madrid → Rome → Washington
Timetable, Rome time
11:45FR 9602 from Madrid at the gate
11:00UA 885 to Washington leaves the gate
23 h 15 apart on the timetable, overnight
UA 885 leaves 23 h 15 after FR 9602 arrives on the timetable: more than half a day, so not a connection we count.