FR 9602 then XZ 2813 at Fiumicino
Madrid → Rome → Catania
Timetable, Rome time
16:40FR 9602 from Madrid at the gate
13:30XZ 2813 to Catania leaves the gate
20 h 50 apart on the timetable, overnight
XZ 2813 leaves 20 h 50 after FR 9602 arrives on the timetable: more than half a day, so not a connection we count.