FR 9674 then FR 999 at Fiumicino
Madrid → Rome → Valencia
Timetable, Rome time
12:50FR 9674 from Madrid at the gate
10:35FR 999 to Valencia leaves the gate
21 h 45 apart on the timetable, overnight
FR 999 leaves 21 h 45 after FR 9674 arrives on the timetable: more than half a day, so not a connection we count.