FR 994 then EW 887 at Fiumicino
Valencia → Rome → Cologne
Timetable, Rome time
22:30FR 994 from Valencia at the gate
19:45EW 887 to Cologne leaves the gate
21 h 15 apart on the timetable, overnight
EW 887 leaves 21 h 15 after FR 994 arrives on the timetable: more than half a day, so not a connection we count.