FR 994 then EW 889 at Fiumicino
Valencia → Rome → Cologne
Timetable, Rome time
22:30FR 994 from Valencia at the gate
15:20EW 889 to Cologne leaves the gate
16 h 50 apart on the timetable, overnight
EW 889 leaves 16 h 50 after FR 994 arrives on the timetable: more than half a day, so not a connection we count.