FR 994 then FR 5814 at Fiumicino
Valencia → Rome → Eindhoven
Timetable, Rome time
12:50FR 994 from Valencia at the gate
12:40FR 5814 to Eindhoven leaves the gate
23 h 50 apart on the timetable, overnight
FR 5814 leaves 23 h 50 after FR 994 arrives on the timetable: more than half a day, so not a connection we count.