FR 994 then FR 9673 at Fiumicino
Valencia → Rome → Madrid
Timetable, Rome time
14:25FR 994 from Valencia at the gate
12:35FR 9673 to Madrid leaves the gate
22 h 10 apart on the timetable, overnight
FR 9673 leaves 22 h 10 after FR 994 arrives on the timetable: more than half a day, so not a connection we count.