FR 994 then U2 2965 at Fiumicino
Valencia → Rome → Berlin
Timetable, Rome time
22:30FR 994 from Valencia at the gate
17:30U2 2965 to Berlin leaves the gate
19 h apart on the timetable, overnight
U2 2965 leaves 19 h after FR 994 arrives on the timetable: more than half a day, so not a connection we count.