U2 4941 then W4 6013 at Fiumicino
Paris Orly → Rome → Madrid
Timetable, Rome time
19:40U2 4941 from Paris Orly at the gate
17:15W4 6013 to Madrid leaves the gate
21 h 35 apart on the timetable, overnight
W4 6013 leaves 21 h 35 after U2 4941 arrives on the timetable: more than half a day, so not a connection we count.