U2 5079 then AZ 1745 at Fiumicino
Berlin → Rome → Catania
Timetable, Rome time
19:55U2 5079 from Berlin at the gate
13:20AZ 1745 to Catania leaves the gate
17 h 25 apart on the timetable, overnight
AZ 1745 leaves 17 h 25 after U2 5079 arrives on the timetable: more than half a day, so not a connection we count.