U2 5079 then FR 3181 at Fiumicino
Berlin → Rome → Barcelona
Timetable, Rome time
19:55U2 5079 from Berlin at the gate
10:25FR 3181 to Barcelona leaves the gate
14 h 30 apart on the timetable, overnight
FR 3181 leaves 14 h 30 after U2 5079 arrives on the timetable: more than half a day, so not a connection we count.