U2 5079 then VY 6009 at Fiumicino
Berlin → Rome → Barcelona
Timetable, Rome time
19:55U2 5079 from Berlin at the gate
14:00VY 6009 to Barcelona leaves the gate
18 h 05 apart on the timetable, overnight
VY 6009 leaves 18 h 05 after U2 5079 arrives on the timetable: more than half a day, so not a connection we count.