U2 5079 then W4 6027 at Fiumicino
Berlin → Rome → Valencia
Timetable, Rome time
19:55U2 5079 from Berlin at the gate
12:35W4 6027 to Valencia leaves the gate
16 h 40 apart on the timetable, overnight
W4 6027 leaves 16 h 40 after U2 5079 arrives on the timetable: more than half a day, so not a connection we count.