U2 6104 then AZ 76 at Fiumicino
Munich → Rome → Barcelona
Timetable, Rome time
16:15U2 6104 from Munich at the gate
14:05AZ 76 to Barcelona leaves the gate
21 h 50 apart on the timetable, overnight
AZ 76 leaves 21 h 50 after U2 6104 arrives on the timetable: more than half a day, so not a connection we count.