U2 6104 then VY 6007 at Fiumicino
Munich → Rome → Barcelona
Timetable, Rome time
16:15U2 6104 from Munich at the gate
12:35VY 6007 to Barcelona leaves the gate
20 h 20 apart on the timetable, overnight
VY 6007 leaves 20 h 20 after U2 6104 arrives on the timetable: more than half a day, so not a connection we count.